Monochromator-induced glitches in EXAFS data II. Test of the model for a pinhole sample
نویسنده
چکیده
Monochromator-induced glitches m the extended X-ray absorption fine structure (EXAFS) are studied using a pinhole sample . We have collected more detailed beam-profile data that enabled us to do a better simulation of the glitch shape. Applying the model we developed earlier, we obtain excellent agreement between the simulation and the experimental pinhole glitch . We point out that the EXAFS glitch is not caused by the crystal glitch alone, but is induced by the vertical movement of the glitch in space across the beam, as the energy is changed when the sample is non-uniform . Several methods have been suggested to minimize the glitch amplitude. Here we note that glitches can be reduced using two double-monochromators or a pair of strip array detectors for the incident and transmitted beams.
منابع مشابه
Rotation of X-ray polarization in the glitches of a silicon crystal monochromator
EXAFS studies on dilute samples are usually carried out by collecting the fluorescence yield using a large-area multi-element detector. This method is susceptible to the 'glitches' produced by all single-crystal monochromators. Glitches are sharp dips or spikes in the diffracted intensity at specific crystal orientations. If incorrectly compensated, they degrade the spectroscopic data. Normaliz...
متن کاملEXAFS studies of the chemical state of lead and copper in corrosion products formed on the brass surface in potable water.
EXAFS measurements in the corrosion deposits were performed on Bell Labs-UIUC beamline X16C at the NSLS at Brookhaven National Laboratory in grazing incidence fluorescence mode at room temperature. EXAFS in the reference Cu and Pb metal foils, malachite, cerussite and hydrocerussite were measured in transmission. Sagittally focused second crystal in the double crystal Si (111) monochromator all...
متن کاملBayesian Two-Sample Prediction with Progressively Type-II Censored Data for Some Lifetime Models
Prediction on the basis of censored data is very important topic in many fields including medical and engineering sciences. In this paper, based on progressive Type-II right censoring scheme, we will discuss Bayesian two-sample prediction. A general form for lifetime model including some well known and useful models such asWeibull and Pareto is considered for obtaining prediction bounds ...
متن کاملScanning and Energy Dispersive EXAFS Studies of Nickel Alkene Oligomerisation Catalysts
In situ EDE and scanning EXAFS studies of homogeneous aikene oligomerisation catalysts are reported. EDE spectra were acquired either on Station 9.3 at the SRS Daresbury Laboratory using a bent Si(220) crystal monochromator (Ni and Br K-edges) or on ID24 at the ESRF using a Si(ll1) monochromator in a Bragg geometry (Ni K-edge). The catalysts studied were derived fiom mixtures of Ni(acach (acac ...
متن کاملThe effect of nursing care plan based on “Roy Adaptation model” on psychological adaptation in patients with diabetes type II
Background: Applying “Roy Adaptation Model" in caring of patients with diabetes needs a context based planning using the principles of this model. But no study has been done up to now in Iranian nursing context Aim: To examine the effect of employing a care plan based on the Roy Adaptation Model on psychological adaptation in patient with type II diabetes. Methods: This clinical trial was perfo...
متن کامل